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Table of Content

(Total Video Instruction Time Given in Parentheses)

Structure

Hydrocarbons

  • Aliphatic
    • Alkanes
      • Normal or n-Alkanes, Video (35:00)
      • Iso and Neo Common Names, Video (20:43)
      • Common Names of Alkyl Radical, Video (19:43)
      • Systematic Names of Alkyl Radicals, Video (10:05)
      • Branched Acyclic Alkanes: Systematic Nomenclature, Video (16:20)
      • Mono Cyclic Alkanes, Video (17:01)
      • Cis and Trans on Mono Cyclic Alkanes, Video (27:50)
      • Cis and Trans on Bicyclic Alkanes: Von-Baeyer Nomenclature, Video (24:01)
      • Endo, Exo, Syn and Anti on Bicyclic Alkanes, Video (36:15)
      • Acyclic Alkanes with one Chiral Center: R, S Nomenclature, Video (36:52)
      • Acyclic Alkanes with two or more Chiral Centers, Video (41:08)
      • Alkanes Review, Video (35:55)
    • Alkenes
      • Acyclic Alkenes: E-Z Nomenclature, Video (28:36)
      • Mono Cyclic Alkenes, Video (4:56)
      • Most and Least Stable Alkenes (Answers Hidden), Video (11:02)
      • Cumulenes, Video (14:27)
    • Alkynes
      • Alkynes and Alkenynes, Video (14:07)
  • Aromatic
    • Benzenoid Aromatics, Video (10:29)
    • Non-Benzenoid Aromatics, Video (10:53)
    • Anti and Non-Aromatic Hydrocarbons, Video (7:22)

Alcohol Derivatives

  • Acyclic Alkyl Halides, Video (6:52)
  • Acyclic Alcohols, Video (14:30)
  • Acyclic Thiols, Video (7:23)
  • Amines and Ammonium Salts, Video (12:38)
  • Acyclic Ethers, Video (9:47)

Carbonyl Compounds

  • Acyclic Aldehydes and Ketones, Video (15:17)
  • Hydrates, Hemiacetals, Hemiketals, Acetals, Ketals, Enols, Enolates, Enol Ethers and Oxoniums, Video (36:20)
  • Imines, Enamines, Hydrazones, and Oximes, Video (23:08)

Carboxylic Acid Derivatives

  • Carboxylic Acids: Common and Systematic Nomenclature, Video (23:59)

Carbon Dioxide Derivatives

  • Carbonates

Combination Functional Groups

  • Smallest Example of a Functional Group, Video (11:15)
  • Line Notation, Video (21:20)
  • Benzene Derivatives, Video (14:27)
  • Carbohydrates, (Open Form, Fischer Projection) Video (53:48), (Closed Form, Haworth Projection) Video (43:48), (Disaccharides) Video (53:11)
  • alpha-Ammonium Carboxylates (Amino Acids), Video (27:21)
  • Dipeptides with Essential Alpha-Amino Acids, Video (17:00)
  • Lipids
  • Steroids
  • Aromatic Heterocycles, Video (2:05)
  • Nucleotides
  • Nucleic Acids
  • Polymers

Reactivity

Alkanes

  • Free Radical Halogenation of Alkanes
  • Cracking
  • Combustion

Alkyl Halides

  • SN2, SN1, E1 and E2 Reactions of Alkyl Halides, Video (34:53)
  • Dehydrohalogenation of Vicinal Dihalides (Under E2 Reactions?)

Alcohols

  • Oxidation of Alcohols, Video (31:39)
  • Dehydration of Alcohols to Alkenes (Answers Hidden), Video (27:20)

Ethers

  • SN1 and SN2 Reactions of Epoxides, Video (17:25)
  • Synthesis of Ethers from Alcohols and Alkyl Halides

Alkenes

  • Alkene Addition Reactions, Video (13:14)
  • Free Radical Substitution on Alkenes (Under Free Radical Halogenation Reactions?)
  • Hydrohalogenation of Conjugated Alkadienes (Under Alkene Addition Reactions?)
  • Pericyclic Reactions
    • Cyclo Additions-Diels Alder, Video (11:15)
    • Electrocyclic Reactions, Video (28:00)
    • Sigma Tropic Rearrangements-Claisen and Cope Rearrangements
    • The Ene Reaction
  • Synthetic Polymers

Alkynes

  • Alkyne Substitution Reactions (Under SN2 Reactions?)
  • Alkyne Addition Reactions, Video (15:06)

Carbonyl Compounds

  • Mechanism: The acid catalyzed synthesis of the ketal of cyclohexanone and ethane-1,2-diol, Video (20:13)
  • Mechanism:  The acid catalyzed synthesis of the enol ether of 3-methylbutanone and methanol
  • Mechanism:  The synthesis of the enamine of 2,2-dimethylcyclohexanone and pyrrolidine
  • Mechanism:  The synthesis of triethylamine by reductive amination
  • Mechanism:  The synthesis of pentan-3-ol from bromoethane and propanal
  • Reductive Addition to Aldehydes and Ketones, Video (37:52)
  • Reduction of Carbonyls to Methylenes
  • Mechanism:  The Wittig reaction of iodomethane and cyclohexanone
  • Wittig Reaction, Video (40:05)
  • Enol and Enolate Reactions, Video (25:32)
  • Aldol Reactions, Video (13:06)
  • Additions to alpha,beta-Unsatured Carbonyl Compounds
  • Michael Addition and Robison Annulation Reactions (Under Aldol)
  • Carbohydrate Synthesis and Degradation

Benzene

  • Synthesis of Benzene Derivatives, Video (6:45)
  • Oxidation and Reduction of Benzene Derivatives
  • Synthesis of Phenols
  • Synthesis and Substitution of Arenediazonium Salts (Under Synthesis of Benzene Derivatives?)

Carboxylic Acid Derivatives

  • Synthesis of Carboxylic Acids: The Baeyer-Villiger Reaction, The Beckmann Rearrangement (Rearrangement Reactions?)
  • Mechanism:  The synthesis of caprolactone by the acid catalyzed Fischer esterifaction of 6-hydroxyhexanoic acid
  • Mechanism:  The reaction of propanoic acid and methamamine with DCC
  • Synthesis of Carboxylic Acid Derivatives from Carboxylic Acids, Video (27:56)
  • Mechanism:  The reduction of N,N-diethylethanamide with diisobutylaluminum hydride
  • Mechanism:  The reduction of methyl propanoate with methyl magnesium chloride and hydronium workup
  • Reduction of Carboxylic Acid Derivatives, Video (41:47)
  • Claisen Condensation Reactions, Video (25:08)

Carbonate Derivatives

  • Synthesis of Carbonate Derivatives: The Hofmann Rearrangement

Multistep Syntheses

  • Synthesis: Leaf Alcohol, Video (4:17)
  • Synthesis:  Cascarillic Acid
  • Synthesis:  A Limonene Isomer
  • Synthesis:  A Norbonane Derivative
  • Synthesis:  Acetaminophen
  • Synthesis:  Ibuprofen
  • Synthesis:  A Hormone Herbicide
  • Synthesis:  A Synthetic Musk
  • Synthesis:  Steroid Rings
  • Synthesis:  Two Artificial Sweeteners
  • Synthesis:  Optical Polarizers

Characterization

Physical Properties

  • Acidity, pKa
  • Boiling Point
  • Melting Point
  • Solubility
  • Optical Rotation

Nuclear Magnetic Resonance

  • 1H NMR of C6H14O Isomers (Answers Hidden), Video (36:07)
  • 13C NMR of Acyclic Alkanes (Answers Hidden), Video (23:57)

Infrared Spectroscopy

  • IR of C4H8O2 Isomers (Answers Hidden), Video (4:22)

Ultra-Violet Visible Spectroscopy

  • Conjugated and Isolated Alkadienes, Video (12:49)
  • Graphical Huckel Method, Video (29:13)

Mass Spectrometry

 

 

 

 

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